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发表于 2009-8-15 19:19:17
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Contents
3 C' H. `: @/ k) \1 E1. Introduction.............................................................................................................................................. 3
- n$ D0 f# k4 L* O& E1.1 Conventional Vulcanisation, Semi-Efficient Vulcanisation and Efficient Vulcanisation .............. 3
& l# @, ?. _6 l# K. d1 v# \: e/ Y1 c1.2 Measuring Cure ............................................................................................................................... 3: e r) u1 o3 i( T% `7 E% {
1.3 Test Equipment and Conditions ...................................................................................................... 50 l5 ~- m' K) d9 e4 F! x* z4 h
2. Curing Systems ........................................................................................................................................ 5# o3 n+ H5 ?3 [( B/ X
2.1 Sulfur Curing Systems .................................................................................................................... 5
2 Y4 E/ W" M( E% n. t% `$ L2.1.1 Accelerators ........................................................................................................................ 5& A7 r3 O9 U4 v
2.1.2 Sulfur Donors ................................................................................................................... 12
8 z( s% z! d f" f/ ?% b2.2 Cures for Speciality Elastomers ........................................................................................................ 16
2 |( c6 c+ F- A/ l/ j: f: j7 O2.2.1 Cure Systems for EPDM .................................................................................................. 164 K3 h, n0 Z" L4 F9 v
2.2.2 Cure Systems for Nitrile Rubber ...................................................................................... 19" m. X) ?/ _" ^6 h
2.2.3 Cure Systems for Polychloroprene ................................................................................... 19! `2 m& v ]+ N5 }: C/ U
2.2.4 Cure Systems for Butyl and Halobutyl Rubber ............................................................... 21
9 T/ Y7 w. j/ J' D! g3 ?- c( z4 l# Q2.3 Peroxide Cure Systems ................................................................................................................. 26
9 f0 v' y1 O: ^0 F! W; F2.3.1 Peroxide Vulcanisation of EPDM .................................................................................... 298 O1 H' r8 y; r
2.4 Sulfur Free Curing Systems .......................................................................................................... 30
$ \) W! N7 R8 A x- R' ~2.4.1 Phenolic Curatives, Benzoquinone Derivatives and Bismaleimides ............................... 30
7 f6 u, w6 F6 a5 V2.4.2 Vulcanisation by Triazine Accelerators ............................................................................ 30
- W! _6 v, Z( |( n2 y9 ~2.4.3 Urethane Crosslinkers ......................................................................................................308 J8 c' [4 ~5 e0 I; A6 R
2.4.4 Other Crosslinking Agents ............................................................................................... 318 t+ d& A6 {) `) @4 F ~; b
2.5 New Developments ....................................................................................................................... 31
; e! J" p+ z- Z! L3. Some Practical Examples with Varying Cure Systems ...................................................................... 32- W0 G4 d0 r, Z+ K m
3.1 Tyres .............................................................................................................................................. 32
6 O4 r" u) W( R: D A3.1.1 Tread ................................................................................................................................. 32
: U. A5 ?+ \' P" c! i: O3.1.2 Tread Base or Sub Tread .................................................................................................. 346 i, l6 @* x' Z" s0 {2 h4 u' T4 ~( m
3.1.3 Belts .................................................................................................................................. 34
2 t% s1 c2 Q' J$ A2 z3.1.4 Sidewall ............................................................................................................................ 35
/ S5 w9 f9 P6 p% A3 z) ?9 A9 z, V: x3.1.5 Carcass .............................................................................................................................. 35
3 Z, V* Y/ z. B6 m2 z: C3.1.6 Bead .................................................................................................................................. 35
9 g3 \( g% m- T( i3.1.7 Apex ................................................................................................................................. 361 [/ t/ ?6 j0 }8 }/ c' o* u: d
3.1.8 Cap-Ply ............................................................................................................................. 365 r, l3 d/ F9 Y2 }
3.1.9 Inner Liner ........................................................................................................................ 37
" h8 a' Q0 _# w/ c9 {; M; ]9 f, _3.2 Industrial Rubber Products ........................................................................................................... 372 w: L- ^% L0 \. f
3.2.1 Conveyor Belt Cover - NR ............................................................................................... 38
8 j$ B- J, b) C3 |3.2.2 Engine Mount - NR ..........................................................................................................40% \8 o4 _/ a" _
3.2.3 Tank Pad – NR/SBR/BR Blend ........................................................................................ 42! }0 R9 C! @ G; e
3.2.4 Oil Seal - NBR ................................................................................................................. 44
- X1 p& D/ ?% P4. Concluding Remarks ............................................................................................................................. 44
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2 y- N3 H: L8 @- m' f就这一点儿,后面全是文摘,参考
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4 s: V. _- v0 y7 M& O“橡胶新人,很想学习些关于硫化体系的东西,可是我的下载权限不够……谢谢!”& {+ c8 ?6 Q' ^6 x6 |* R
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