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橡胶原材料知识-生胶篇-第八章4 x' O& |& b" u+ A1 N8 f
乙烯丙烯酸酯橡胶0 V$ K: L# y& \: ]9 e/ A7 a
Ethylene acrylic elastomers-AEM-Vamac®* K+ q( N. @, Y) p
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Vamac® ethylene acrylic elastomer (AEM) products are a comprehensive family of heat and fluid resistant elastomers for flexible applications ranging from hoses, dampers and boots to seals and gaskets. Vamac® provides significant performance advantages over low temperature ACM and HNBR grades, including better low temperature resistance and high temperature performance up to 175°C. Compared to HNBR substantial cost savings can be achieved.; s. k7 I7 D3 w# E8 l6 d
Vamac® ethylene acrylic elastomers can be made into cured compounds that have excellent resistance to high temperatures and good resistance to automotive fluids such as transmission fluids and engine oils.$ u7 @. J1 b0 ^. ~
LOW-TEMPERATURE PERFORMANCE8 |+ ~7 ?' M6 b4 D1 c
The low-temperature performance of Vamac® surpasses that of most other heat- and oil-resistant polymers. Typical compounds are flexible at temperatures of -40℃(-40℉). For flexibility at even lower temperatures, plasticizers can be used. + B7 g8 M( U% Q" ?
RESISTANCE TO FLUIDS
; z: o( i0 P+ k5 A% S' \" AEnd products based on Vamac® have excellent resistance to hot oils and hydrocarbon- or glycol-based lubricants, transmission fluids, and power steering fluids. Low oil swell can be obtained with proper Vamac® grade selection and compounding.
/ C+ m& P, \( U: l7 s" e, xVamac® is not recommended for use in components immersed in gasoline or highly aromatic fluids, but can be used as a cover material in fuel line applications to reduce costs.# Q0 S! F% q, W, P8 B( T& m
EXCELLENT VIBRATION DAMPING ABILITY* i; w0 ~# v3 y9 @/ L0 v! N
The high vibrational damping characteristic of Vamac® remains nearly constant over broad ranges of temperature, frequency and amplitude.; h. w0 u. z, \; G# y. x( H1 N
LOW FIRE/SMOKE HAZARD
; C1 k+ G4 b( ]Vamac® ethylene acrylic elastomer is not inherently resistant to burning. However, when properly compounded, a wire jacket of Vamac® will pass the demanding UL-44 vertical wire flame test, generating very low smoke compared to other flame-resistant materials and provide non-halogen off-gases in fire situations.# H5 j3 I0 k, j# m
HIGH-TEMPERATURE DURABILITY
" J$ f& H- t: O$ `# jParts made with Vamac® retain elasticity and remain functional after continuous air-oven exposures. Typical times and temperatures are six weeks at 160℃(330℉),18months at 121℃(250℉) or five days at 204℃(400℉). Vamac® Ultra IP provides improved high-temperature durability (6 weeks at 175℃(347℉))4 x3 c: R4 n% P* U1 r1 A
COMPRESSIVE STRESS RELAXATION" c* |$ Y$ S& ]$ g! Z
Vamac® compounds perform exceptionally well in seal and gasket applications and have shown good performance in engine oils out to 5000 hours at 150℃(302℉).6 B) h3 I/ O. G3 I8 h1 }1 i
GRADE SELECTION CRITERIA& m& _1 n6 U9 S& T# B8 r9 v
Basic Heat and Oil Swell Characteristics
/ { R: x) m8 A) O# b! eCompounds based on Vamac® G and Vamac® DP typically exhibit IRM903 oil swell of 40-60%. If compounded appropriately, the polymer can withstand 6 weeks of continuous use at 175℃(347℉), maintaining 50% elongation. Vamac® is generally assigned an ASTM D2000/SAE200 rating of EG or EF.
2 w3 B, |7 D& l1 t2 ]$ m$ i3 l- w! R$ XFor Reduced Oil Swell
3 ?# U# m. }1 t3 Q4 BFor reduced oil swell, Vamac® GLS exhibits about one half the IRM903 oil swell of its G counterpart. However, its lower oil swell is accompanied by a reduction (by 7℃) in low-temperature flexibility. l+ P# X- o+ b. f1 p2 \" y
For High-Temperature Dynamic Performance
% O6 e% V' u! }0 H! hCompounds with Vamac® GXF have improved tensile properties and dynamic fatigue resistance at elevated temperatures compared to Vamac® G. At 150℃, tensile strength, ultimate elongation are 12% higher; DeMattia fatigue results show over a 150% improvement. Cure times for Vamac® GXF are slightly longer, compression sets higher than Vamac® G.
Z5 T. V3 u! L8 yFor Molding or Extrusion# P5 I- y3 T* l. W5 @: ]/ x
Vamac® Ultra IP can vastly improve productivity through reduced mold fouling, scrap, improved hot tear resistance and cycle time compared with core Vamac® G product. With higher viscosity, Vamac® Ultra IP provides superior compound dispersion with a 1-pass mix and extruded profile stability.
3 k: x: Z/ r0 A$ u2 s9 G2 q' d& VFor Low-Temperature, Dynamic Performance
n' d; s4 x" a, |( ^* IVamac® Ultra LT delivers low temperature flexibility down to -40℃ and lower in service with fewer performance-draining plasticizers, especially for use in automotive hoses and boots as well as dampers where functional performance is required throughout a thermal range as wide as -54℃ to 160℃.- e: y: A$ ~3 _: ` I8 r$ {$ k; O/ I
Vamac® invites opportunities to help you formulate compounds to meet specific processing./ x# }* G+ Z2 M6 y2 \/ Y- b: o
Curing Method ; E2 C# h: C6 M
Diamine-cured terpolymer, Vamac® G, is used for most applications. If postcure is impractical or undesirable, Vamac® DP peroxide-cured dipolymer can be used.
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5 }- _+ o+ r) qNote:The above from http://www.dupontelastomers.com. |
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