纳米Si3N4粉体表面改性及其在橡胶中的应用研究

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纳米Si3N4粉体表面改性及其在橡胶中的应用研究
张卫昌[1] 章于川[1] 夏迎松[2] 张海潮[2]PDF
. o+ M# x- {0 `" M: U( f$ m[1]安徽大学化学化工学院安徽省绿色高分子重点实验室,安徽合肥230039 [2]安徽宁国中鼎密封件有限公司,安徽宁国242300

摘　要:该文选择含羧基（-COOH）和腈基（-CN）的聚合物作为表面改性剂，研究了对纳米Si3N4粉体湿法改性工艺的影响因素，采用TGA对纳米Si3N4粉体改性效果进行了表征，确定了最佳改性时间（120min左右）、改性温度（60℃左右）和改性剂用量（5％左右）。把在此工艺条件下表面改性后的纳米Si3N4粉体加入橡胶中，当改性纳米Si3N4粉体的用量为生胶的0．5％（质量比）时，所制备的Si3N4／NBR复合材料的撕裂强度、拉伸强度、耐油性能均得到明显的提高。[著者文摘]
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关键词:纳米氮化硅 表面改性剂 丁腈橡胶 耐油性
) S( i2 z1 ]. X/ \分类号:　TQ330.383[著者标引]文献标识码：B文章编号：1671-8232（2008）10-0011-04栏目信息：科研与创新
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Study on the surface modification of nano-Si3N4 powder and application in rubberZHANG Wei-chang, ZHANG Yu-chuan , XIA Ying-song, ZHANG Hai-chao 1. Key laboratory of Environment-friendly polymer materials, School of Chemistry ＆ Chemical engineering, Anhui University, Hefei 230039; 2. Anhui Ningguo Zhongding Sealing Parts Co. Ltd. , Ningguo 242300Abstract:This article choices polymers containing carboxyl（-COOH） and nitrile group （-CN） as surface treatment agent. A method by which the nano-Si3N4 was modified with this surface treatment agent was studied. The surface characterization of the modified Si3N4 was investigated by TGA. The suitable technical factors（ time about 120 min, temperature about 60℃ and surface treatment agent dosage about 5% ） were obstained. Composites containing nano-Si3N4 powder and nitrile-butadiene rubber（NBR） were prepared by direct blending. The mechanical properties of the composites were investigated. The results showed that, when nano-Si3N4 powder dosage was 0. 5 phr, the tensile strength, tear strength and bear oil capability of NBR were improved in evidence.[著者文摘]

- X* j2 B/ f1 e5 r+ U% C. hKey words:nano-Si3N4 powder; surface treatment agent; NBR; bear oil capability, coating
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收稿日期:　修订日期:　基金资助:
作者简介:张卫昌（1979-），男，安徽滁州人，硕士研究生，现就读于安徽大学化学化工学院，主要从事高分子基橡胶复合材料方面的研究。